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Synthesis 2014; 46(18): 2524-2532
DOI: 10.1055/s-0034-1378230
DOI: 10.1055/s-0034-1378230
paper
The ‘Mikami’-Catalyst in Enantioselective Diels–Alder Reactions of Juglone-Based Dienophiles with Different 1-Oxygenated Dienes: An Investigation on the Substitution Pattern Dependent Regioselectivity
Further Information
Publication History
Received: 09 April 2014
Accepted after revision: 06 May 2014
Publication Date:
25 June 2014 (online)
Abstract
A mechanistic study investigating the substitution pattern depending regioselectivity of enantioselective BINOL-Ti-catalyzed Diels–Alder reactions of juglone-based dienophiles with 1-oxygenated dienes is reported. The different influences of residues both on the diene as well as on the dienophiles are investigated giving a detailed picture of their role on the regioselectivity.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084.
- Supporting Information
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