Synthesis 2014; 46(06): 722-739
DOI: 10.1055/s-0033-1340829
short review
© Georg Thieme Verlag Stuttgart · New York

Recent Applications of C 1-Symmetric Bis(oxazoline)-Containing Ligands in Asymmetric Catalysis

Steven O’Reilly
Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Dublin 4, Ireland   Fax: +353(1)7162501   Email: p.guiry@ucd.ie
,
Patrick J. Guiry*
Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Dublin 4, Ireland   Fax: +353(1)7162501   Email: p.guiry@ucd.ie
› Author Affiliations
Further Information

Publication History

Received: 29 November 2013

Accepted after revision: 27 January 2014

Publication Date:
19 February 2014 (online)


Abstract

Bis(oxazolines) are a well-known class of ligands in the area of asymmetric catalysis. Most of these ligands are C 2-symmetric due to the synthetic route employed for their synthesis. This review article summarizes the recent progress of the closely related, but relatively unexplored, C 1-symmetric bis(oxazoline) ligands and compares and contrasts the two where applicable.

1 Introduction

2 Bis(oxazolines)

2.1 Bis(oxazolines) with Differentially Substituted Oxazolines

2.2 Bis(oxazolines) with Asymmetrically Substituted Linking Unit

2.3 Bis(oxazolines) with Differentially Substituted Oxazolines and Asymmetrically Substituted Linking Unit

3 Conclusion

 
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