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Synthesis 2013; 45(6): 753-758
DOI: 10.1055/s-0032-1316858
DOI: 10.1055/s-0032-1316858
paper
Synthesis of Metallo-Supramolecular Polymers Using 5,5′-Linked Bis(1,10-Phenanthroline) Ligands
Further Information
Publication History
Received: 25 December 2012
Accepted after revision: 31 January 2013
Publication Date:
14 February 2013 (online)
Abstract
5,5′-Linked bis(1,10-phenanthroline)s were synthesized as new bidentate ligands by a palladium-catalyzed Suzuki-type cross-coupling reaction. Coordination of the ligands to Cu(II), Ni(II), Ag(I), and Zn(II) ions resulted in metallo-supramolecular polymer formation. The 1:1 complexation of the ligands and the metal ions was confirmed by UV-vis titration experiments. The high molecular weights of more than 105 Da, caused by the high complexation constants, were confirmed by the SEC-Viscometry-RALLS method.
Key words
bis(1,10-phenanthroline)s - metallo-supramolecular polymers - complexation - cross-coupling - palladiumSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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References
- 1a Whittell GR, Hager MD, Schubert US, Manners I. Nat. Mater. 2010; 10: 176
- 1b Bandyopadhyay A, Sahu S, Higuchi M. J. Am. Chem. Soc. 2011; 133: 1168
- 1c Yu S.-C, Kwok C.-C, Chan W.-K, Che C.-M. Adv. Mater. (Weinheim, Ger.) 2003; 15: 1643
- 1d Higuchi M, Kurth DG. Chem. Rec. 2007; 7: 203
- 1e Han FS, Higuchi M, Kurth DG. Adv. Mater. (Weinheim, Ger.) 2007; 19: 3928
- 1f Han FS, Higuchi M, Kurth DG. J. Am. Chem. Soc. 2008; 130: 2074
- 1g Higuchi M. Polym. J. 2009; 41: 511
- 1h Wojtecki RI, Meador MA, Rowan SJ. Nat. Mater. 2010; 10: 14
- 1i Burnworth M, Tangl L, Kumpferl JR, Duncan AJ, Beyer FL, Fiore GL, Rowan SJ, Weder C. Nature (London) 2011; 472: 334
- 1j Kwok C.-C, Yu S.-C, Sham IH. T, Che C.-M. Chem. Commun. 2004; 2758
- 1k Sato T, Higuchi M. Chem. Commun. 2012; 48: 4947
- 1l Ravindra RP, Higuchi M, Negishi Y, Tsukuda T, Kurth DG. Polym. J. 2010; 42: 336
- 2a Reed JE, Neidle S, Vilar R. Chem. Commun. 2007; 4366
- 2b Reed JE, White AJ, Neidle S, Vilar R. Dalton Trans. 2009; 2558
- 2c Rajput C, Rutkaite R, Swanson L, Haq I, Thomas JA. Chem. Eur. J. 2006; 12: 4611
- 2d Talib J, Green C, Davis KJ, Urathamakul T, Beck JL, Aldrich-Wright JR, Ralph SF. Dalton Trans. 2008; 1018
- 2e Hudson ZD, Sanghvi CD, Rhine MA, Ng JJ, Bunge SD, Hardcastle KI, Saadein MR, MacBeth CE, Eichler JF. Dalton Trans. 2009; 7473
- 2f Ruthkosky M, Castellano FN, Meyer GJ. Inorg. Chem. 1996; 35: 6406
- 2g He A, Zhong C, Huang H, Zhou Y, He Y, Zhang HJ. Luminescence 2008; 128: 1291
- 2h Saravani H, Rezvani AR, Mansouri G, Rad AR. S, Khavasi HR, Hadadzadeh H. Inorg. Chim. Acta 2007; 360: 2829
- 2i Anbu S, Kandaswamy M. Polyhedron 2011; 30: 123
- 3a Velten U, Lahn B, Rehahn M. Macromol. Chem. Phys. 1997; 198: 2789
- 3b Velten U, Rehahn M. J. Chem. Soc., Chem. Commun. 1996; 2639
- 3c Bernhard S, Takada K, Jenkins D, Abruna HD. Inorg. Chem. 2002; 41: 765
- 3d Bernhard S, Goldsmith JI, Takada K, Abruna HD. Inorg. Chem. 2003; 42: 4389
- 3e Velten U, Rehahn M. Macromol. Chem. Phys. 1998; 199: 127
- 3f Vidal PL, Divisia-Blohorn B, Bidan G, Hazemann JL, Kern JM, Sauvage JP. Chem. Eur. J. 2000; 6: 1663
- 3g Sauvage JP. Acc. Chem. Res. 1998; 31: 611
- 4a Pakhomova SV, Proskurnin MA, Chernysh VV, Kononets MY, Ivanova EK. J. Anal. Chem. 2001; 56: 910
- 4b Proskurnin MA, Chernysh VV, Pakhomova SV, Kononets MY, Sheshenev AA. Talanta 2002; 57: 831
- 5 Hossain MD, Sato T, Higuchi M. Chem. Asian J. 2013; 8: 76
-
6a Miyaura N, Suzuki A. Chem. Rev. 1995; 95: 2457
- 6b Han FS, Higuchi M, Kurth DG. Org. Lett. 2007; 9: 559
- 7 Hissler M, Connick WB, Geiger DK, McGarrah JE, Lipa D, Lachicotte RJ, Eisenberg R. Inorg. Chem. 2000; 39: 447
- 8 Eggert JP. W, Luning U, Nather C. Eur. J. Org. Chem. 2005; 1107