Copper-Catalyzed N–N Bond Formation by Homocoupling of Ketoximes via N–O Bond Cleavage: Facile, Mild, and Efficient Synthesis of Azines

Mi-Na Zhao; Hao Liang; Zhi-Hui Ren; Zheng-Hui Guan

doi:10.1055/s-0031-1290779

Synthesis, Inhaltsverzeichnis

Synthesis 2012; 44(10): 1501-1506
DOI: 10.1055/s-0031-1290779

special topic

Copper-Catalyzed N–N Bond Formation by Homocoupling of Ketoximes via N–O Bond Cleavage: Facile, Mild, and Efficient Synthesis of Azines

Authors

Mi-Na Zhao

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. of China, eMail: guanzhh@nwu.edu.cn
Hao Liang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. of China, eMail: guanzhh@nwu.edu.cn
Zhi-Hui Ren

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. of China, eMail: guanzhh@nwu.edu.cn
Zheng-Hui Guan*

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. of China, eMail: guanzhh@nwu.edu.cn

Abstract

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Abstract

A facile, mild, and efficient copper-catalyzed homocoupling of ketoximes involving N–O bond cleavage in the presence of sodium bisulfite (NaHSO₃) has been developed. This reaction shows good functional group tolerance and affords a broad scope of azines in high yields.

Key words

copper - homocoupling - ketoxime - azine - NaHSO₃

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Referenzen

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