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Synfacts 2011(3): 0278-0278
DOI: 10.1055/s-0030-1259498
DOI: 10.1055/s-0030-1259498
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Novel Ligands for Asymmetric [3+2] Cycloaddition of Enones
C. Zhang, S.-B. Yu, X.-P. Hu*, D.-Y. Wang, Z. Zheng*
Dalian Institute of Chemical Physics and Graduate School of Chinese Academy of Sciences, Beijing, P. R. of China
Further Information
Publication History
Publication Date:
16 February 2011 (online)
Significance
A novel family of chiral ferrocenyl P,S-ligands was successfully developed and applied to a highly endo-selective catalytic enantioselective [3+2] cycloaddition of azomethine ylides with both cyclic and acyclic enones. The desired chiral pyrrolidine derivatives were obtained with high yields and enantioselectivities.