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Synlett 2025; 36(10): 1423-1429
DOI: 10.1055/a-2530-5032
DOI: 10.1055/a-2530-5032
letter
Cathode-Induced C–H Functionalization of 1,4-Quinones with Aryldiazonium Salts
Authors
We thank the support of the National Natural Science Foundation of China (52103272) and the Natural Science Foundation of Zhejiang Province (LQ21E030004).
Abstract
A mild and green method was developed for the aryl-monosubstituted or aryl-disubstituted quinones compounds under electrochemical conditions. We found that the existence of O2 and trace water may be beneficial to the formation of product. This protocol exhibits a broad range of functional tolerance and satisfactory yields for accessing aryl-substituted quinones under ambient conditions at room temperature.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2530-5032.
- Supporting Information (PDF)
Publication History
Received: 03 November 2024
Accepted after revision: 31 January 2025
Accepted Manuscript online:
31 January 2025
Article published online:
20 March 2025
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