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Synlett 2025; 36(10): 1408-1412
DOI: 10.1055/a-2527-1554
DOI: 10.1055/a-2527-1554
letter
Improving the Performance of Palladium-Catalyzed Telomerization of 1,3-Butadiene with Malonate by Alcohol Solvent
This work was financially supported by the National Nature Science Foundation of China (22271094), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0610000), the Innovation Program of the Shanghai Municipal Education Commission (2023ZKZD37), and the Fundamental Research Funds for the Central Universities.
Abstract
Using alcohol instead of largely excessive malonate as the solvent can improve the performance of palladium-catalyzed telomerization of 1,3-butadiene with malonate. Under the basic conditions, the main reaction was not overwhelmed by the telomerization of 1,3-butadiene with methanol solvent. With this method, methyl (E)-deca-4,9-dienoate, the intermediate for the synthesis of 10-hydroxy decanoic acid, undecanedioic acid, and 11-hydroxy undecanoic acid, can be prepared from the telomerization of 1,3-butadiene with dimethyl malonate in good yield.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2527-1554.
- Supporting Information
Publication History
Received: 15 January 2025
Accepted after revision: 28 January 2025
Accepted Manuscript online:
28 January 2025
Article published online:
12 March 2025
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