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Synthesis 2025; 57(05): 978-990
DOI: 10.1055/a-2508-3355
DOI: 10.1055/a-2508-3355
paper
RNHSO2F as Reliable Azasulfene Precursors for the Construction of Sulfamates
The authors are thankful for the financial support from the State Grid Corporation of China through their Science and Technology Project (5200-202320132A-1-1-ZN).
Abstract
The utilization of NH-sulfamoyl fluorides (RNHSO2F) as reliable SuFEx synthons for the construction of various sulfamate esters is reported. By using potassium fluoride as base, we were able to convert RNHSO2F into azasulfene intermediates under mild conditions and guarantee their further efficient ligation with phenols and alcohols.
Keywords
SuFEx - NH-sulfamoyl fluorides - sulfamate esters - azasulfene intermediates - potassium fluorideSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2508-3355.
- Supporting Information
Publikationsverlauf
Eingereicht: 29. November 2024
Angenommen nach Revision: 26. Dezember 2024
Accepted Manuscript online:
26. Dezember 2024
Artikel online veröffentlicht:
29. Januar 2025
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