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Synthesis 2022; 54(23): 5168-5185
DOI: 10.1055/a-1930-6979
DOI: 10.1055/a-1930-6979
short review
Recent Advances for Chiral Sulfoxides in Asymmetric Catalysis
The financial support from the Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University (2020ZD02), Hubei Key Laboratory of Biologic Resources Protection and Utilization, Hubei Minzu University (PT012101), State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences (KF2021-06), Hubei Key Laboratory of Processing and Application of Catalytic Materials, Huanggang Normal University (202203504), and the Innovation Fund of Key Laboratory of Green Chemical Process, Ministry of Education, Wuhan Institute of Technology (GCX202102) are greatly appreciated.
Dedicated to Prof. Dr. Carsten Bolm at RWTH and Prof. Dr. Shu Kobayashi at the University of Tokyo.
Abstract
Chiral sulfoxide is considered to be an ideal candidate ligand for transition-metal-catalyzed asymmetric reactions due to its ease of synthesis, stability, and exceptional S-stereological orientation control. This paper reviews the different types of asymmetrical reactions with chiral sulfoxide ligands in recent years, as well as a discussion of efficient methods for the preparation of some enantiomerically pure sulfoxides.
1 Introduction
2 Chiral Sulfoxides as Ligands in Metal-Catalyzed Asymmetric Catalysis
3 Synthesis of Chiral Sulfoxides
4 Conclusions
Publication History
Received: 13 June 2022
Accepted after revision: 25 August 2022
Accepted Manuscript online:
25 August 2022
Article published online:
27 October 2022
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