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Synthesis 2022; 54(21): 4773-4783
DOI: 10.1055/a-1801-2595
DOI: 10.1055/a-1801-2595
special topic
Asymmetric C–H Functionalization
Enantioselective Cobalt-Catalyzed C–H Functionalization
We thank the National Natural Science Foundation of China (21871145 and 22188101), Tianjin Applied Basic Research Project and Cutting-Edge Technology Research Plan (19JCZDJC37900), the Haihe Laboratory of Sustainable Chemical Transformations, and Frontiers Science Center for New Organic Matter (63181206) for financial support.
Abstract
Co-catalyzed C–H functionalization has received great attention due to the high earth abundance, low biotoxicity, and unique reactivity of cobalt; enantioselective control of these reactions has been a formidable challenge. Various efficient strategies have recently been developed for enantioselective Co-catalyzed C–H functionalization, but there is no topical review of this field. Herein, we give a detailed summary of this rapidly growing field, highlighting critical progress, current challenges, and future trends.
1 Introduction
2 Enantioselective C–H Functionalization via Low-Valent Co Catalysis
2.1 Chiral Diphosphines for Enantioselective Control
2.2 Chiral Monophosphines or N-Heterocyclic Carbenes for Enantioselective Control
3 Enantioselective C–H Functionalization via High-Valent Co Catalysis
3.1 Chiral Acids for Enantioselective Control
3.2 Chiral Cp Ligands for Enantioselective Control
4 Conclusions and Outlook
Key words
enantioselective - cobalt catalysis - C–H functionalization - chiral acid - chiral cyclopentadienyl ligandPublication History
Received: 17 February 2022
Accepted after revision: 17 March 2022
Accepted Manuscript online:
17 March 2022
Article published online:
12 May 2022
© 2022. Thieme. All rights reserved
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For selected reviews on transition-metal-catalyzed C–H functionalization, see:
For selected reviews on 3d-transition-metal-catalyzed C–H functionalization, see:
For selected reviews on Co-catalyzed C–H functionalization, see:
For reviews that summarize enantioselective Co-catalyzed C–H functionalization into subsections, see:
For selected reviews on Co-involved photo- or electrocatalysis, see:
For recent progress from Zhang group, see:
For selected examples on diphosphine-enabled enantioselective Co-catalyzed transformation of π-unsaturated compounds, see:
For relevant examples on asymmetric Rh-catalyzed versions, see:
For Rh-catalyzed formation of four-membered cyclobutanones, see:
For Rh-catalyzed version, see:
For selected reviews on C(sp3)–H activation, see: