Synthesis 2021; 53(18): 3279-3289
DOI: 10.1055/a-1468-1455
special topic
Bond Activation – in Honor of Prof. Shinji Murai

C–H Bond Functionalization Using Pd- and Au-Supported Catalysts with Mechanistic Insights of the Active Species

Tamao Ishida
a   Department of Applied Chemistry for Environment, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1–1 Minami-osawa, Hachioji, Tokyo 192-0397, Japan
,
Zhenzhong Zhang
b   RIKEN Center for Sustainable Resource Science, Hirosawa, Wako, Saitama 351-0198, Japan
,
Haruno Murayama
c   Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
,
Eiji Yamamoto
c   Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
,
Makoto Tokunaga
c   Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
› Author Affiliations
This work was financially supported by a Grant-in-Aid for Scientific Research (B) (Grant no. 19H02755) from the Ministry of Education, Culture, Science, Sports and Technology, Japan, and by the Japan Society for the Promotion of Science (JSPS) and National Natural Science Foundation of China (NSFC) under the Joint Research Program (JRP with NSFC, Grant no. JPJSJRP 20191804).


Abstract

The process of C–H functionalization has been extensively studied as a direct C–C bond-forming reaction with high atomic efficiency. Efforts have also been made on such reactions by using supported catalysts, which are superior in terms of catalyst separation from the reaction mixture and reusability. In this review, an overview of C–H functionalization reactions, especially those involving Pd- and Au-supported catalysts, is presented. In particular, we discuss reaction mechanisms, active species, leaching, reusability, etc.

1 Introduction

2 Types of Supported Metal Catalysts and Their Active Species

3 Modes of C–H Bond Activation

4 Oxidative C–H C–H Coupling of Aryl Compounds

5 C–H C–H Coupling Where One Side Is Aromatic

6 C–H Acylation of Aromatic Compounds and Related Reactions

7 Conclusion



Publication History

Received: 15 March 2021

Accepted after revision: 26 March 2021

Accepted Manuscript online:
26 March 2021

Article published online:
26 April 2021

© 2021. Thieme. All rights reserved

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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