Towards Reaction Selectivities of Imines and Aziridines

Xue Long Hou; Jie Wu; Ren Hua Fan; Chang Hua Ding; Zhi Bin Luo; Li Xin Dai

doi:10.1055/s-2006-926220

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Synlett 2006(2): 181-193
DOI: 10.1055/s-2006-926220

ACCOUNT

Towards Reaction Selectivities of Imines and Aziridines

Xue Long Hou*^a,b, Jie Wu^a, Ren Hua Fan^b, Chang Hua Ding^b, Zhi Bin Luo^a, Li Xin Dai*^a
^a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. of China
^b Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. of China
e-Mail: xlhou@mail.sioc.ac.cn;

Further Information

Publication History

Received 31 July 2005
Publication Date:
24 January 2006 (online)

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Abstract

Several simple and convenient transformations of imines and aziridines under mild conditions have been developed, rendering access to several kinds of β-amino derivatives, α-amino nitriles and phosphonates, aziridines, and conjugated dienes from imines and aziridines under neutral and metal-free conditions very conveniently. High stereoselectivities are realized in most reactions based upon mechanistic considerations.

Key words

transformations - imines - aziridines - mild conditions

References and Notes

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1

Current address: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P. R. of China