Boron-Substituted Building Blocks in Diels-Alder and Other Cycloaddition Reactions

Gerhard Hilt; Patrick Bolze

doi:10.1055/s-2005-872084

REVIEW

Boron-Substituted Building Blocks in Diels-Alder and Other Cycloaddition Reactions

Gerhard Hilt*, Patrick Bolze
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany
Fax: +49(6421)2825677; e-Mail: Hilt@chemie.uni-marburg.de;

Abstract

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Abstract

Boron-containing building blocks are among the most prominent starting materials in several transformations based on their wide range of synthetic applications. Over the last decade various cycloaddition reactions were reported where boron-containing 1,3-dienes or boron-containing dienophiles were used. Combined with the broad follow-up chemistry, target-oriented as well as diversity-oriented syntheses could be established.

1 Introduction
2 Boron-Functionalised 1,3-Dienes
2.1 Boron in Position 1
2.2 Boron in Position 2
3 Boron-Functionalised Dienophiles
3.1 Alkenyl Boron Reagents
3.2 Alkynyl Boron Reagents
4 Boron Reagents in 1,3-Dipolar Cycloaddition
5 Miscellaneous
6 Outlook

Key words

boron - cycloaddition - cyclotrimerisation - Diels-Alder reaction - 1,3-dipole

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