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Synthesis 2003(18): 2753-2762
DOI: 10.1055/s-2003-44359
DOI: 10.1055/s-2003-44359
REVIEW
© Georg Thieme Verlag Stuttgart · New YorkEpoxide Oxidations: A Valuable Tool in Organic Synthesis
Weitere Informationen
Received
18 June 2003
Publikationsdatum:
10. Dezember 2003 (online)
Publikationsverlauf
Publikationsdatum:
10. Dezember 2003 (online)
Abstract
This article focuses on stoichiometric and catalytic epoxide oxidations and their scope in organic synthesis. The work on Bi/O2-catalysed oxidation, developed in our group over the last last ten years, is presented with various reactions leading to several oxidised compounds.
1 Introduction
2 Epoxide Oxidations Involving C-C Bond Cleavage
2.1 Stoichiometric Oxidations
2.2 Catalytic Oxidations
3 Epoxide Oxidations Without C-C Bond Cleavage
3.1 Stoichiometric Oxidations
3.2 Catalytic Oxidations
4 Conclusion
Key words
epoxides - oxidations - catalysis - bismuth - oxygen
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