Palladium-Catalyzed Allylation of Carbonyl Compounds with Various Allylic Compounds Using In-InCl3 in Aqueous Media

Taeg-Su Jang; Gyochang Keum; Soon Bang Kang; Bong Young Chung; Youseung Kim

doi:10.1055/s-2003-38059

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Synthesis 2003(5): 0775-0779
DOI: 10.1055/s-2003-38059

SPECIALTOPIC

Palladium-Catalyzed Allylation of Carbonyl Compounds with Various Allylic Compounds Using In-InCl₃ in Aqueous Media

Taeg-Su Jang^a, Gyochang Keum^a, Soon Bang Kang^a, Bong Young Chung^b, Youseung Kim*^a
^a Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang P. O. Box 131, Seoul 130-650, Korea
Fax: +82(2)9585189; e-Mail: yosekim@kist.re.kr;
^b Department of Chemistry, Korea University, Seoul 136-701, Korea

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Publikationsverlauf

Received 15 February 2003
Publikationsdatum:
21. März 2003 (online)

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Abstract

Various allylic compounds can be effectively applied to palladium-catalyzed allylation of carbonyl compounds via the formation of π-allylpalladium(II) intermediates and their transmetalation with indium in the presence of indium trichloride in aqueous media.

Key words

allylation - palladium - indium - indium trichloride - aqueous

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