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Synlett 2001; 2001(5): 0597-0600
DOI: 10.1055/s-2001-13353
DOI: 10.1055/s-2001-13353
letter
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data processing and storage.Tandem Glycol Cleavage-Intramolecular [4 + 2] Cycloadditions Mediated by Dess-Martin periodinane
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2001 (online)

The product distribution on oxidation of vicinal unsaturated diols using Dess-Martin periodinane (DMP) under various conditions is investigated. The process depends upon 1,2-diol-stereochemistry and constitutes a useful method for glycol fission offering molecular complexity.
oxidative cleavage - tandem reactions - Dess-Martin periodinane