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Synlett 2001; 2001(4): 0447-0457
DOI: 10.1055/s-2001-12309
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Controlled Reactivity of Phosphonates by Temporary Silicon Connection

Bogdan Iorga* , Philippe Savignac
  • *Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, DCPH, Ecole Polytechnique, 91128 Palaiseau Cedex, France; Tel + 33 1 69 33 45 79; Fax + 33 1 69 33 39 90; E-mail: savignac@poly.polytechnique.fr
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Publication Date:
31 December 2001 (online)

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In this review a summary of the different syntheses of trimethylsilylphosphonates is given. Their chemical reactivity in the light of their synthetic utility leading to numerous types of functionalized phosphonates is described. The material is presented according to the role played by the trimethylsilyl group.

phosphonate carbanion - Peterson reaction - silicon - halogenation - alkylation

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