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Synlett 1996; 1996(11): 1019-1028
DOI: 10.1055/s-1996-5656
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Phosphorhydrazide Macrocycles and Cryptands

Anne-Marie Caminade1 , Jean Pierre Majoral2
  • 1Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077 Toulouse Cédex, France, Fax (01133) 61 55 30 03, e-mail caminade@lcctoul.lcc-toulouse.fr
  • 2Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077 Toulouse Cédex, France, Fax (01133) 61 55 30 03, e-mail majoral@lcctoul.lcc-toulouse.fr
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Publication Date:
31 December 2000 (online)

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Several ways of synthesis of N-N-P-N-N containing macrocycles are described. These methods allowed the isolation of more than 120 macrocycles of different sizes, incorporating phosphorus atoms in several coordinences (tri, tetra, penta coordination), several heteroatoms (silicon, zirconium, titanium) and different types of functions (C=N, P-Cl, P-N3). The complexation ability of these macrocycles as well as their versatile reactivity, leading to more complex systems such as multimacrocycles and phosphorus cryptands are also described.

macrocycle - multimacrocycle - cryptand - phosphorhydrazide