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Synlett 1995; 1995(10): 1085-1086
DOI: 10.1055/s-1995-5170
DOI: 10.1055/s-1995-5170
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Enantioselective Pauson-Khand Reactions Mediated by a Chiral Amine N-Oxide
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Publication History
Publication Date:
31 December 2000 (online)
The first example of an asymmetric version of the Pauson-Khand cyclisation promoted solely by a chiral amine N-oxide, brucine N-oxide, is reported. This amine N-oxide has been utilised in the Pauson-Khand annulation to give excellent yields and good enantiomeric excesses of cyclopentenone at low temperature.
Asymmetric Pauson-Khand Reaction - chiral N-oxide - cyclopentenone - asymmetric annulation