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Synlett 1995; 1995(7): 723-725
DOI: 10.1055/s-1995-5048
DOI: 10.1055/s-1995-5048
letter
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Diastereoselective Reactions of gem-Bismetallic Derivatives
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
In this report, we show that various chelated organo-gem-bismetallics can react with two different electrophiles leading to a new asymmetric stereogenic center with a good diastereoselectivity.
organo-gem-bismetallic - α-stannylated organozinc halide - configurational stability - stereogenic center