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Synlett 1995; 1995(7): 723-725
DOI: 10.1055/s-1995-5048
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Diastereoselective Reactions of gem-Bismetallic Derivatives

Fan Wang, Jie Tang, Lydie Labaudinière, Ilane Marek* , Jean-F. Normant
  • *Laboratoire de Chimie des Organoéléments, Université P. et M. Curie, 4 Place Jussieu, Tour 44-45, F-75252 Paris Cédex 05, France, Fax 33-1-4427 7150
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Publication Date:
31 December 2000 (online)

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In this report, we show that various chelated organo-gem-bismetallics can react with two different electrophiles leading to a new asymmetric stereogenic center with a good diastereoselectivity.

organo-gem-bismetallic - α-stannylated organozinc halide - configurational stability - stereogenic center

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