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Synthesis 1971; 1971(12): 617-638
DOI: 10.1055/s-1971-21780
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One Hundred Years of Sulfenic Acid Chemistry II b. Substitution and Cyclization Reactions of Sulfenyl Halides

Engelbert KÜHLE*
  • *Wissenschaftliches Hauptlaboratorium, Farbenfabriken Bayer AG, D-509, Leverkusen-Bayerwerk
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Publication Date:
12 September 2002 (online)

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The substitution reactions of Sulfenic acid halides are particularly sulfenylations of OH, SH, NH, and CH compounds. In this part of the review, the applicability of the individual methods is dealt with in each case; in addition, attention is paid to abnormal reaction sequences. Bis-sulfenyl chlorides, ω-chlorocarbonylsulfenyl chlorides, and possibly substituted chloromethanesulfenyl chlorides can be called upon for cyclization reactions.