Advances in Selected Heterocyclization Methods

Abstract

This Account summarizes efforts in our group toward synthesis of heterocycles in the past decade. Selected examples of transannulative heterocyclizations, intermediate construction of reactive compounds en route to these important motifs, and newer developments of a radical approach are outlined.

1 Introduction

2 Transannulative Heterocyclization

2.1 Rhodium-Catalyzed Transannulative Heterocyclization

2.2 Copper-Catalyzed Transannulative Heterocyclization

3 Synthesis of Heterocycles from Reactive Precursors

3.1 Synthesis of Heterocycles from Diazo Compounds

3.2 Synthesis of Heterocycles from Alkynones

4 Radical Heterocyclization

4.1 Light-Induced Radical Heterocyclization

4.2 Light-Free Radical Heterocyclization

7 Conclusion

Key words

transannulative heterocyclization - heterocycles - radical heterocyclization - transition-metal-catalyzed heterocyclization.

Publikationsverlauf

Eingereicht: 23. Dezember 2022

Angenommen nach Revision: 13. Februar 2023

Artikel online veröffentlicht:
10. März 2023

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