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Synthesis 2022; 54(09): 2251-2257
DOI: 10.1055/s-0040-1719881
DOI: 10.1055/s-0040-1719881
paper
Nickel-Catalyzed Reductive Cross-Coupling of Oxalates Derived from α-Hydroxy Carbonyls with Vinyl Bromides
Authors
This research was supported by the National Natural Science Foundation of China (No. 21871173).
Abstract
A nickel-catalyzed cross-electrophile coupling is disclosed in which a range of vinyl bromides were utilized as electrophiles with oxalates derived from α-hydroxy carbonyls as precursors to carbonyl radical coupling partners. This method is compatible with a broad range of functional groups, providing a complementary solution for the construction of β,γ-unsaturated carbonyl compounds.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1719881.
- Supporting Information (PDF)
Publikationsverlauf
Eingereicht: 30. Oktober 2021
Angenommen nach Revision: 09. Dezember 2021
Artikel online veröffentlicht:
10. Februar 2022
© 2022. Thieme. All rights reserved
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- 15 A preliminary study showed that the oxalate derivative of an α-hydroxy amide was also a viable substrate. For details of this reaction, see the Supporting Information.