Synthesis 2020; 52(23): 3549-3563
DOI: 10.1055/s-0040-1707239
short review
© Georg Thieme Verlag Stuttgart · New York

Progress on Iridium-Catalyzed Hydrosilylation of Alkenes and Alkynes

Weiwei Gao
a  State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. of China   Email: [email protected]
,
a  State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. of China   Email: [email protected]
b  State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing, 100191, P. R. of China
› Author Affiliations
This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 21702015, 21871023), the Big Science Project, Beijing University of Chemical Technology (XK180301), the Fundamental Research Funds for the Central Universities (buctrc201719), and the State Key Laboratory of Natural and Biomimetic Drugs (Peking University).
Further Information

Publication History

Received: 29 May 2020

Accepted after revision: 07 July 2020

Publication Date:
18 August 2020 (online)


Abstract

Hydrosilylation of multiple carbon–carbon bonds is a well-known process for the construction of organosilicon compounds. Nowadays, precious metal catalysts, especially platinum complexes, still occupy dominant positions in such processes. However, one important member of the precious metal family, iridium, is less used in this field. As early research mainly focused on developing stable and effective iridium catalysts, recent advances have disclosed the specific efficiency of simple iridium catalytic systems in the synthesis of functional organo­silicon compounds. This short review summarizes the utilization of iridium complexes for the hydrosilylation of alkenes and alkynes, with an emphasis on the recent advances published in the last decade.

1 Introduction

2 Iridium-Catalyzed Hydrosilylation of Alkenes

3 Iridium-Catalyzed Hydrosilylation of Alkynes

4 Conclusions and Perspectives

Key words

iridium

catalysis

hydrosilylation

alkenes

alkynes

 
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