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Synthesis 2021; 53(04): 666-672
DOI: 10.1055/s-0040-1705970
DOI: 10.1055/s-0040-1705970
feature
Synthesis of 6-Adamantyl-2-pyridone and Reversible Hydrogen Activation by the Corresponding Bis(perfluorophenyl)borane Complex
Autoren
This work was supported by the Deutsche Forschungsgemeinschaft (DFG; German Research Foundation) (GE 3117/1-1).
Abstract
We herein describe the two-step synthesis of 6-adamantyl-2-pyridone from 1-acetyladamantane. The borane complex derived from 6-adamantyl-2-pyridone and the Piers borane liberates dihydrogen at 60 °C. The reverse reaction, hydrogen activation by the formed pyridonate borane is accomplished under mild conditions. The mechanism of the hydrogen activation is studied by DFT computations.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1705970.
- Supporting Information (PDF) (opens in new window)
Publikationsverlauf
Eingereicht: 27. August 2020
Angenommen nach Revision: 05. Oktober 2020
Artikel online veröffentlicht:
10. November 2020
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