Synthesis 2021; 53(02): 344-347
DOI: 10.1055/s-0040-1705950
special topic
Functional Organic Molecules

One-Pot Synthesis of a Cyclic Pyrene Octamer from Two Bifunctionalized Pyrene Monomers

Peifeng Mei
,
,
Akinobu Matsumoto
,
,
This work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI Grant Nos. JP20H00379 (H.Y.), JP19H04584, JP20H02711, and JP19K22112 (N.A.), CREST, Japan Science and Technology Agency (JST) Grant No. JPMJCR15F1 (H.Y.), and the Nara Institute of Science and Technology (NAIST) Special Fund (P.M.). P.M. is grateful to the Japan Student Services Organization (JASSO) for a scholarship.


Abstract

A 2,2′-tert-butyl-5,9-6′,8′-cyclooctameric pyrenylene ([8]CP) was synthesized by a one-pot Suzuki–Miyaura cross-coupling reaction from two kinds of bifunctionalized monomers, as a rare example of a cyclic octamer. The octameric molecular structure of [8]CP was revealed by single-crystal X-ray diffraction analysis.

Supporting Information



Publication History

Received: 20 August 2020

Accepted after revision: 17 September 2020

Publication Date:
26 October 2020 (online)

© 2020. Thieme. All rights reserved

Georg Thieme Verlag KG
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