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Synthesis 2020; 52(06): 853-860
DOI: 10.1055/s-0039-1690763
DOI: 10.1055/s-0039-1690763
paper
Synthesis of Bis-BINOL Derivatives: Linking via the 3-, 4-, or 5-Position by Generation of Suitable C 1-Symmetric Precursors
Funding by the Fonds der Chemischen Industrie (Liebig-Fellowship Li 193/02 to J.N.) and Evonik Industries AG (PhD fellowship to M.K.) is gratefully acknowledged.Further Information
Publication History
Received: 23 October 2019
Accepted after revision: 20 November 2019
Publication Date:
10 December 2019 (online)
In memory of Prof. Dieter Enders
Abstract
Bis-BINOL derivatives have proven highly useful in applications such as chemosensing or organocatalysis. In this account, we describe strategies for the linking of BINOL units via the 3-, 4-, or 5-positions, showing that unique synthetic strategies are necessary to address each position. We report the synthesis of suitable C 1-symmetric precursors, which are generated either by monohalogenation or by monodeprotection of C 2-symmetric starting materials, and their subsequent coupling to give linked bis-BINOL derivatives.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690763.
- Supporting Information
- CIF File
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