Synthesis 2018; 50(05): 1015-1019
DOI: 10.1055/s-0036-1589153
psp
© Georg Thieme Verlag Stuttgart · New York

Practical Synthesis of a PCP-Type Pincer Ligand and Its Metal Complexes­

Kazutaka Matoba*
a  Chemical Research Laboratories, Nissan Chemical Industries, Ltd., Funabashi, Chiba, 274-8507, Japan   Email: [email protected]
,
b  Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan   Email: [email protected]
,
Shunsuke Nishimura
b  Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan   Email: [email protected]
,
Kazuya Arashiba
b  Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan   Email: [email protected]
,
b  Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan   Email: [email protected]
,
b  Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan   Email: [email protected]
› Author Affiliations
The present project is supported by CREST, JST (CREST-JPMJCR1541). We thank JSPS KAKENHI Grant Numbers JP17H01201 and JP15H05798 in Precisely Designed Catalysts with Customized Scaffolding. A.E. is a recipient of the JSPS Predoctoral Fellowships for Young Scientists.
Further Information

Publication History

Received: 02 November 2017

Accepted after revision: 18 November 2017

Publication Date:
14 December 2017 (online)


Abstract

A synthetic method for N-heterocyclic carbene- and phosphine-based PCP-type pincer ligand is described on a large scale. Some transition-metal complexes bearing the PCP-type pincer ligand are prepared and characterized by X-ray crystal structure analysis.

Supporting Information

 
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