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Synthesis 2017; 49(17): 3895-3904
DOI: 10.1055/s-0036-1588996
DOI: 10.1055/s-0036-1588996
special topic
Hydroboration and Diboration of Internal Alkynes Catalyzed by a Well-Defined Low-Valent Cobalt Catalyst
Authors
Further Information
Publication History
Received: 13 February 2017
Accepted after revision: 17 March 2017
Publication Date:
06 April 2017 (online)
Published as part of the Special Topic Cobalt in Organic Synthesis
Abstract
The use of a simple well-defined low-valent cobalt(I) catalyst [HCo(PMe3)4] capable of performing the regio- and stereoselective hydroboration of internal alkynes is reported. Extension to the diboration of internal alkynes is also related using the same reaction conditions.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588996.
- Supporting Information (PDF)
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