Synthesis 2017; 49(17): 3895-3904
DOI: 10.1055/s-0036-1588996
special topic
© Georg Thieme Verlag Stuttgart · New York

Hydroboration and Diboration of Internal Alkynes Catalyzed by a Well-Defined Low-Valent Cobalt Catalyst

Laura Ferrand
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
,
Ye Lyu
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
,
Alejandro Rivera-Hernández
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
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Brendan J. Fallon
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
,
Muriel Amatore
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
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Corinne Aubert
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
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Marc Petit*
Sorbonne Universités, UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Case 229, 4 Place Jussieu, 75252 Paris Cedex 05, France   Email: marc.petit@upmc.fr
› Author Affiliations
Further Information

Publication History

Received: 13 February 2017

Accepted after revision: 17 March 2017

Publication Date:
06 April 2017 (eFirst)

Published as part of the Special Topic Cobalt in Organic Synthesis

Abstract

The use of a simple well-defined low-valent cobalt(I) catalyst [HCo(PMe3)4] capable of performing the regio- and stereoselective hydroboration of internal alkynes is reported. Extension to the diboration of internal alkynes is also related using the same reaction conditions.

Supporting Information

 
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