Synthesis 2017; 49(17): 3925-3930
DOI: 10.1055/s-0036-1588986
special topic
© Georg Thieme Verlag Stuttgart · New York

Large-Scale Cobalt-Catalyzed Cross-Couplings of Functionalized Bench-Stable Arylzinc Pivalates with (Hetero)Aryl and Alkenyl Halides­

Maximilian S. Hofmayer
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, Haus F, 81377 München, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
,
Jeffrey M. Hammann
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, Haus F, 81377 München, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
,
Ferdinand H. Lutter
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, Haus F, 81377 München, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
,
Paul Knochel*
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, Haus F, 81377 München, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
› Author Affiliations
Further Information

Publication History

Received: 13 February 2017

Accepted after revision: 09 March 2017

Publication Date:
18 April 2017 (eFirst)

Published as part of the Special Topic Cobalt in Organic Synthesis

Abstract

A robust and scalable CoCl2-catalyzed cross-coupling between functionalized arylzinc pivalates and various electron-poor (hetero)aryl and alkenyl halides is reported.

Supporting Information

 
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