Synthesis 2017; 49(05): 973-980
DOI: 10.1055/s-0036-1588088
short review
© Georg Thieme Verlag Stuttgart · New York

Recent Applications of Solid-Supported Ammonium Fluorides in Organic Synthesis

Daniela Lanari
a  Dipartimento di Scienze Farmaceutiche, Università di Perugia, Via del Liceo 1, 06123 Perugia, Italy
,
Oriana Piermatti
b  Laboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy   Email: luigi.vaccaro@unipg.it
,
Chiara Morozzi
a  Dipartimento di Scienze Farmaceutiche, Università di Perugia, Via del Liceo 1, 06123 Perugia, Italy
,
Stefano Santoro
b  Laboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy   Email: luigi.vaccaro@unipg.it
,
Luigi Vaccaro*
b  Laboratory of Green Synthetic Organic Chemistry, Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy   Email: luigi.vaccaro@unipg.it
› Author Affiliations
Further Information

Publication History

Received: 21 August 2016

Accepted after revision: 07 October 2016

Publication Date:
10 November 2016 (online)


Abstract

This review summarizes recent contributions on the use of fluoride catalysts immobilized on polymer supports. Besides the commercially available Amberlyst fluoride, TBAF on silica gel, and TBAF on alumina, that have proved widely useful for several interesting and valuable synthetic C–N, C–O, and C–C bond transformations, novel catalysts based on the DABCO moiety have allowed access to very useful, new transformations.

1 Introduction

2 Polystyryl-DABCOF2

3 Polystyryl-DABCOF

4 Amberlyst Fluoride (Amb-F)

5 TBAF on Alumina or on Silica Gel

6 Conclusion

 
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