Synthesis 2016; 48(16): 2612-2618
DOI: 10.1055/s-0035-1561605
special topic
© Georg Thieme Verlag Stuttgart · New York

Rhodium-Catalyzed Enantioselective Addition of Tricyclopropylboroxin to N-Sulfonylimines

Takahiro Nishimura*
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan   Email: tnishi@kuchem.kyoto-u.ac.jp
,
Tomotaka Nagai
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan   Email: tnishi@kuchem.kyoto-u.ac.jp
,
Ryosuke Takechi
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan   Email: tnishi@kuchem.kyoto-u.ac.jp
,
Yusuke Ebe
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan   Email: tnishi@kuchem.kyoto-u.ac.jp
› Author Affiliations
Further Information

Publication History

Received: 05 January 2016

Accepted after revision: 10 March 2016

Publication Date:
14 April 2016 (eFirst)

Abstract

A hydroxorhodium complex coordinated with a chiral diene ligand efficiently catalyzed the asymmetric addition of tricyclopropylboroxin to N-sulfonylimines in high yields and high enantioselectivities.

Supporting Information

 
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