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DOI: 10.1055/s-0035-1561264
Organic Catalysts for Photocontrolled Polymerizations
Publication History
Received: 28 October 2015
Accepted: 24 November 2015
Publication Date:
21 January 2016 (online)
Abstract
Photocontrolled polymerization is an emerging field of study in which catalysis with organic-based dyes has enabled the practical and inexpensive synthesis of well-defined, spatially and temporally controlled polymeric structures. Herein, we review the current progress in the development of organic catalysts for photoregulated polymerizations. In particular, we highlight advances in metal-free variants of photomediated controlled radical polymerizations. In addition, we examine how the unique properties of these catalysts allow the development of two mechanistically distinct chain-growth polymerizations controlled by light.
1 Introduction
2 Photocontrolled Atom-Transfer Radical Polymerization (ATRP)
3 Photocontrolled Reversible Addition–Fragmentation Chain Transfer (RAFT)
4 Reversible Complexation-Mediated Polymerization (RCMP)
5 Photocontrolled Ring-Opening Metathesis Polymerization (ROMP)
6 Conclusion and Future Outlook
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Organic-based photoredox catalysts have also been utilized as photoinitiators, which is beyond the scope of this review. For examples, see: