Synthesis 2016; 48(04): 493-503
DOI: 10.1055/s-0035-1560556
short review
© Georg Thieme Verlag Stuttgart · New York

Recent Progress in Palladium-Catalyzed Asymmetric Hydrophos­phination

Sumod A. Pullarkat*
Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore   Email: sumod@ntu.edu.sg
› Author Affiliations
Further Information

Publication History

Received: 28 October 2015

Accepted after revision: 24 November 2015

Publication Date:
29 December 2015 (online)


Abstract

Asymmetric construction of P–C bonds is considered to be one of the most powerful methods for the preparation of chiral organophosphorus compounds. This review highlights recent progress in palladium-catalyzed asymmetric hydrophosphination reactions involving activated C=C bonds and diarylphosphines. The main catalytic systems employed for this protocol together with current substrate scope and mechanistic insights are described.

1 Introduction

2 Five-Membered CN/CP Palladacycle Catalyzed Protocols

3 PCP Pincer-Type Catalyst Based Protocols

4 NCN and PCN Pincers as Catalysts

5 Conclusion and Outlook

 
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