Synthesis 2015; 47(05): 587-603
DOI: 10.1055/s-0034-1379892
review
© Georg Thieme Verlag Stuttgart · New York

Reagent and Catalyst Design for Asymmetric Hypervalent Iodine Oxidations

Florian Berthiol*
Département de Chimie Moléculaire (SERCO), UMR-5250, ICMG FR-2607, Université Joseph Fourier, 301 Rue de la Chimie, BP 53, 38041 Grenoble Cedex 9, France   Email: Florian.Berthiol@ujf-grenoble.fr
› Author Affiliations
Further Information

Publication History

Received: 30 October 2014

Accepted after revision: 20 November 2014

Publication Date:
28 January 2015 (eFirst)

Abstract

In this review are compiled the different possible transformations using environmentally benign chiral hypervalent iodine reagents and catalysts. Herein is presented an overview of asymmetric oxidation of sulfides to sulfoxides, oxidation of alkenes, α-functionalization of carbonyl compounds and dearomatization reactions.

1 Introduction

2 Chiral Hypervalent Iodine Reagents

3 Oxidation of Sulfides to Sulfoxides

4 Oxidation of Alkenes

5 α-Functionalization of Carbonyl Compounds

6 Dearomatization Reactions

7 Conclusion

 
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