Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese­, and Indium Organometallics from Functionalized Organic Halides

Abstract

An overview of the most significant synthetic methods currently available for the preparation of functionalized organo­metallic compounds starting from organic halides is presented and illustrated with recent applications.

1 Introduction

2 Metal Insertion

2.1 Magnesium

2.2 Aluminum

2.3 Zinc

2.4 Indium

2.5 Manganese

3 Halogen‒Metal Exchange

3.1 Lithium

3.2 Magnesium

3.3 Zinc

4 Conclusion

Key words

organometallic reagents - functional groups - organic halides - metal insertion - halogen‒metal exchange

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