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Synthesis 2014; 46(17): 2305-2311
DOI: 10.1055/s-0033-1339110
DOI: 10.1055/s-0033-1339110
special topic
Synthesis of Ethyl Arylpropiolates through Palladium-Catalyzed Cross-Coupling Reactions of Aryl Iodides with In Situ Generated Lithium Tetrakis(ethoxycarbonylethynyl)indates
Authors
Further Information
Publication History
Received: 21 February 2014
Accepted after revision: 13 April 2014
Publication Date:
28 May 2014 (online)
Abstract
An efficient synthetic method to access ethyl arylpropiolates has been developed; it involves a palladium-catalyzed cross-coupling reaction between a wide range of aryl iodides and lithium tetrakis(ethoxycarbonylethynyl)indates (0.35 equiv) generated in situ from indium trichloride and alkynides obtained from ethyl propiolate and n-butyllithium.
Key words
cross-coupling - palladium - indium - lithium tetrakis(ethoxycarbonylethynyl)indate - propiolates - catalysisSupporting Information
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10.1055/s-00000084.
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