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Synthesis 2010(19): 3243-3247
DOI: 10.1055/s-0030-1258203
DOI: 10.1055/s-0030-1258203
SPECIALTOPIC
© Georg Thieme Verlag
Stuttgart ˙ New YorkExploring Rhodium-Catalysed Conjugate Addition of Chiral Alkenylboronates Using Chiral Olefin Ligands
Further Information
Received
4 May 2010
Publication Date:
13 August 2010 (online)
Publication History
Publication Date:
13 August 2010 (online)
Abstract
The rhodium-catalysed addition of chiral alkenylboron reagents to prochiral α,β-unsaturated carbonyl acceptors are demonstrated to proceed under ligand control. The highest activities were obtained with chiral olefin ligands and the configuration of the new stereocentre can be predicted by using established models.
Key words
alkenylboronate - conjugate addition - rhodium - catalysis - chiral olefin ligands
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