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Synthesis 2025; 57(12): 1928-1935
DOI: 10.1055/a-2502-8374
DOI: 10.1055/a-2502-8374
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Phenanthrolines as Energy Transfer Photocatalysts for the E → Z Isomerization of Alkenes
Authors
Supported by the National Natural Science Foundation of China (22101279), Beijing National Laboratory for Molecular Sciences (BNLMS2023014), and high level introduction of talent research start-up fund of Putian University (ZY240123).
Abstract
Phenanthrolines have been widely employed as chelating ligands for transition metals. Herein, this study investigates the utility of substituted o-phenanthrolines as independent photosensitizers for the E → Z isomerization of alkenes. The findings underscore the versatility of o-phenanthrolines, providing a straightforward, metal-free, and cost-effective method for synthesizing Z-alkenes.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2502-8374.
- Supporting Information (PDF)
Publication History
Received: 01 October 2024
Accepted after revision: 16 December 2024
Accepted Manuscript online:
16 December 2024
Article published online:
10 February 2025
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