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Synlett 2023; 34(06): 552-560
DOI: 10.1055/a-1894-8136
DOI: 10.1055/a-1894-8136
account
Chemical Synthesis and Catalysis in India
Replacing Anodic Oxygen Evolution Reaction with Organic Oxidation: The Importance of Metal (Oxy)Hydroxide Formation as the Active Oxidation Catalyst
The financial support from the Council of Scientific and Industrial Research (CSIR, Grant no. 01(2977)/19/EMR-II), Government of India is gratefully acknowledged. A.K.S. acknowledges IIT BHU for the research fellowship. D.K. acknowledges the University Grants Commission (UGC), India for the junior research fellowship. B.S. acknowledges the Department of Science and Technology, Ministry of Science and Technology, India (DST-INSPIRE, IF180147) for the research fellowship.
Abstract
Hybrid water electrolysis has been explored for the electrochemical oxidation of biomass, glucose, alcohols, amines, urea, etc. to produce value-added products. The integration of cathodic hydrogen evolution reaction (HER) with anodic organic reaction (AOR) improves the energy efficiency of the electrolyzer by reducing the cell voltage of the overall process. Tremendous progress has been achieved in AOR by using transition-metal-based catalysts. These transition-metal-based catalysts undergo anodic activation in the alkali medium to form metal (oxy)hydroxide [M(O)x(OH)y] as the active catalyst. The atomic and electronic structure of M(O)x(OH)y essentially controls the conversion efficiency and product selectivity for AOR. In this Account, we have described the design of the AOR precatalyst, its anodic activation, and the basic principles of the integration of cathodic HER with AOR. The structural features of the precatalyst and the active catalyst have been described with representative examples. The recent progress and advancement in this field have been explained, and the future scope and challenges associated with AOR have been addressed.
1 Introduction
2 Anodic Organic Oxidation Reactions
3 Activity and Selectivity of Anodic Organic Reaction
4 Anodic Activation of Transition-Metal-Based Catalysts
5 Mechanism of Anodic Organic Oxidation
6 Perspective and Outlook
Key words
hybrid water electrolysis - green hydrogen production - organic oxidation - value-added products - activation of precatalyst - metal (oxy)hydroxidePublication History
Received: 28 April 2022
Accepted: 08 July 2022
Accepted Manuscript online:
08 July 2022
Article published online:
24 August 2022
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