Catalytic Asymmetric Osmium-Free Dihydroxylation of Alkenes

Shixia Su; Chuan Wang

doi:10.1055/a-1325-4092

Synthesis, Inhaltsverzeichnis

Synthesis 2021; 53(07): 1229-1236
DOI: 10.1055/a-1325-4092

short review

Catalytic Asymmetric Osmium-Free Dihydroxylation of Alkenes

Autoren

Shixia Su

^aHefei National Laboratory for Physical Science at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. of China
Chuan Wang ∗

^aHefei National Laboratory for Physical Science at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. of China

^bCenter for Excellence in Molecular Synthesis of CAS, Hefei, Anhui 230026, P. R. of China

Abstract

Alle Artikel dieser Rubrik

Abstract

Asymmetric dihydroxylation of alkenes is one of the cornerstone reactions in organic synthesis, providing a direct entry to optically active vicinal diols, which are not only a subunit in natural products but also versatile building blocks. In recent years, considerable progress in catalytic asymmetric osmium-free dihydroxylation has been achieved. This short review presents a concise summary of the reported methods of catalytic asymmetric osmium-free dihydroxylation.

1 Introduction

2 Iron-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes

3 Manganese-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes

4 Palladium/Gold Bimetallic Nanocluster-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes

5 Enzyme-Catalyzed Asymmetric anti-Dihydroxylation of Alkenes

6 Amine-Catalyzed Asymmetric Formal anti-Dihydroxylation of Enals

7 Diselenide-Catalyzed anti-Dihydroxylation of Alkenes

8 Molybdenum-Catalyzed Asymmetric anti-Dihydroxylation of Allylic Alcohols

9 Phase-Transfer-Catalyzed Asymmetric Dihydroxylation of α-Aryl Acrylates

10 Conclusion

Key words

dihydroxylation - vicinal diol - oxidation - alkene - asymmetric catalysis

Volltext

Referenzen

References

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