Effective and Versatile Functionalisation of Hexamethylbenzene Using N-F Reagents

Stojan Stavber; Petra Kralj; Marko Zupan

doi:10.1055/s-2001-15150

Synlett 2001; 2001(7): 1152-1154
DOI: 10.1055/s-2001-15150

letter

© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Effective and Versatile Functionalisation of Hexamethylbenzene Using N-F Reagents

Stojan Stavber^* , Petra Kralj, Marko Zupan

^*Laboratory of Organic and Bioorganic Chemistry, "Jo ef Stefan" Institute and Department of Chemistry, University of Ljubljana, Jamova 39, 1000 Ljubljana, Slovenia; Fax + 386 1 477 38 11; E-mail: stojan.stavber@ijs.si

Abstract

als PDF herunterladen Alle Artikel dieser Rubrik

Effective direct introduction of alkoxy, amido, azido or halogeno functional groups on the benzylic position in hexamethylbenzene was mediated by the N-F reagents F-TEDA-BF₄, NFTh, NFSi or FP-B800 in the presence of alcohols, carboxylic acids, cyanides or trimethylsilyl derivatives as sources of an external nucleophile.

N-F reagents - hexamethylbenzene - fluorine - amides - ethers

PDF (55 kb)