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Synlett 2001; 2001(7): 1152-1154
DOI: 10.1055/s-2001-15150
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Effective and Versatile Functionalisation of Hexamethylbenzene Using N-F Reagents

Stojan Stavber* , Petra Kralj, Marko Zupan
  • *Laboratory of Organic and Bioorganic Chemistry, "Jo ef Stefan" Institute and Department of Chemistry, University of Ljubljana, Jamova 39, 1000 Ljubljana, Slovenia; Fax + 386 1 477 38 11; E-mail: stojan.stavber@ijs.si
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Publication Date:
31 December 2001 (online)

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Effective direct introduction of alkoxy, amido, azido or halogeno functional groups on the benzylic position in hexamethylbenzene was mediated by the N-F reagents F-TEDA-BF4, NFTh, NFSi or FP-B800 in the presence of alcohols, carboxylic acids, cyanides or trimethylsilyl derivatives as sources of an external nucleophile.

N-F reagents - hexamethylbenzene - fluorine - amides - ethers

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