Synthesis 1996; 1996(7): 821-822
DOI: 10.1055/s-1996-4307
short paper
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Cerium(IV) Catalysis: Efficient Conversion of Epoxides to Thiiranes

N. Iranpoor* , F. Kazemi
  • *Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran, Fax +98(71)20027
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Cerium(IV) as ceric ammonium nitrate (CAN), catalyzes the conversion of different epoxides to their corresponding thiiranes in excellent yields. The reaction occurs efficiently in the presence of ammonium thiocyanate in tert-butanol at room temperature.

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