Download PDF
Synthesis 1994; 1994(8): 813-822
DOI: 10.1055/s-1994-25581
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Aroylation and Acylation of p-Cyanomethylcalix[4]arenes

Shiv Kumar Sharma* , C. David Gutsche
  • *Department of Chemistry, Texas Christian University, Fort Worth, Texas 76129, USA
Further Information

Publication History

Publication Date:
17 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Calix[4]arenes carrying H, tert-butyl, and cyanomethyl groups in the p-positions are converted into tetraesters by aroylation or acylation in the presence of 1-methylimidazole or sodium hydride. Aroylation or acylation of p-cyanomethylcalix[4]arene in the presence of aluminum chloride yield the 1,3-diesters which, upon further aroylation or acylation, provide a variety of tetraesters of mixed functionality.

      >