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Synthesis 1992; 1992(3): 315-319
DOI: 10.1055/s-1992-26099
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Reaction of Cycloalkylphosphorane with Perfluoroalkylnitrile: A New Synthesis of Some Fluorine-Containing Cyclic 1,3-Diketones and Oxo Esters

H. Trabelsi* , A. Cambon
  • *Laboratoire de Chimie Organique de Fluor, U.F.R. Faculté des Sciences, Université de Nice-Sophia Antipolis, Parc Valrose F-06034 Nice-Cedex, France
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Publication Date:
17 September 2002 (online)

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The preparation of some new perfluoroalkyl 1,3-dicarbonyl compounds is reported. The alcoholysis reaction of these 2-perfluoroalkanoylcycloalkanones in the presence or in the absence of base catalysis occurs, involving ring cleavage to yield fluorinated oxo esters.

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