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Synthesis 2021; 53(24): 4614-4620
DOI: 10.1055/a-1559-3346
DOI: 10.1055/a-1559-3346
feature
Iodosulfonylation of Alkynes under Ultrasound Irradiation
This research work was supported by the National Natural Science Foundation of Zhejiang Province (Grant No. LY17B030011).
Abstract
(E)-β-Iodo vinylsulfones are synthesized under ultrasound irradiation using alkynes, sulfonyl hydrazides, potassium iodide and hydrogen peroxide. The key features of this protocol are the speed and efficiency of the reactions, which afford good to excellent yields of the desired products by employing ultrasound as the driving force. Mechanistic studies reveal that a sulfonyl radical intermediate is generated via sulfonyl iodide homolysis.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1559-3346.
- Supporting Information
Publikationsverlauf
Eingereicht: 05. Juli 2021
Angenommen nach Revision: 27. Juli 2021
Accepted Manuscript online:
27. Juli 2021
Artikel online veröffentlicht:
01. September 2021
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