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Synthesis 2004(16): 2620-2624
DOI: 10.1055/s-2004-831209
DOI: 10.1055/s-2004-831209
PAPER
© Georg Thieme Verlag Stuttgart · New York
Indium(III) Halide Mediated S N 2′ Reactions of Substituted Allenols: Synthesis of 2-Halo-1,3-dienes
Further Information
Received
13 April 2004
Publication Date:
02 September 2004 (online)
Publication History
Publication Date:
02 September 2004 (online)
Abstract
Treatment of various substituted allenols with indium(III) halide in benzene gave (Z)- or (E)-2-halo-1,3-dienes in moderate to good yields. In most cases, (2Z)-halo-1,3-dienes were obtained as major products.
Key words
allenol - indium(III) halide - 2-halo-1,3-diene - SN2′ reaction
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